The XT 5% Iridium on Vulcan XC-72R Grade T catalyst manufactured by Fuel Cells ETC is a fine powder that can be used as an electrocatalyst in electrochemical devices and as a heterogeneous catalyst for the synthesis of various organics, such as:
- Formic Acid Oxidation: As the anode catalyst in direct formic acid fuel cells
- Methanol & Ethanol Oxidation: As the anode catalyst in direct alcohol fuel cells
- Hydrogen Oxidation Reaction: As the anode catalyst in alkaline fuel cells
- Chemoselective Hydrogenation of Nitroarenes: Reduction of chloro-nitroarenes or dinitrotoluene to amines while preserving halides or other groups
- Hydrogenation of Quinoline and Heteroaromatics: Effective for ring hydrogenation in pharmaceutical intermediates
- Transfer Hydrogenation: Using donors like isopropanol or formic acid for selective reduction of carbonyls, imines, or other groups in organic synthesis
- Deuteration & Hydrogen Isotope Exchange: C-H activation for selective deuterium labeling of pharmaceuticals and organics using D₂O or other sources
- Selective Hydrogenation of Unsaturated Compounds: Alkenes, alkynes, or α,β-unsaturated carbonyls with good control over over-reduction
- Hydrodeoxygenation (HDO) of Biomass Derivatives:Conversion of furfural or related oxygenates to value-added chemicals/fuels
- Selective Oxidation of Alcohols or Aldehydes: Thermal catalytic oxidation to carbonyl compounds or acids
- CO Oxidation & Gas Purification: Removal of CO from hydrogen streams or environmental applications
- Fine Chemicals & Pharmaceutical Synthesis: Broad use in heterogeneous catalysis for intermediates; recyclable Ir/C reduces metal contamination vs. homogeneous systems
- Decomposition of Formic Acid: To H₂ and CO₂ for hydrogen storage/release applications
- Hydrogenation of Carbonyls: Ketones or aldehydes to alcohols under mild conditions
- Environmental Catalysis: VOC oxidation or pollutant remediation in gas or liquid phase
- Biomass Upgrading & Lignin Derivatives: Selective bond cleavage or stabilization
- and many other electrochemical and non-electrochemical end use cases
This product has a BET surface area of ~200-220 m²/gram. The average crystallite size for Ir nanoparticles is calculated as ~0.57 nm (amorphous or less than 1nm) for this product. The average particle size for this supported catalyst material is ~34.53 microns.
5% Iridium on Vulcan XC-72R Grade T Technical Specification Sheet
| Catalyst Properties | |
| Appearance | Fine, porous black powder |
| Molecular Formula | 5 wt % Ir, 95 wt % high-surface-area carbon black (Vulcan XC-72R) |
| Molecular Weight | Not applicable (heterogeneous composite) |
| Purity | > 99.9% (3N) |
| Particle Morphology | Aggregated clusters of primary Ir nanoparticles |
| Average Particle Size | ~34.53 µm (D₅₀, Laser Diffraction) |
| Particle Size Range | 0 - 100 microns (measured with laser diffraction method) |
| BET Surface Area | ~200 - 220 m2/gram |
| Bulk Density | ~0.25 – 0.35 g cm⁻³ |
| Color | Black |
| Structure | Hexagonal close-packed (fcc) Iridium |
| Database Reference | COD Card No. (1534947); JCPDS No. (06-0598) |
| Space Group | P63/mmc |
| Secondary Phases | None detected (only amorphous carbon support) (via PXRD) |
| Instrument for Powder XRD | Instrument: Rigaku MiniFlex 300/600 Cu-Kα radiation (λ = 1.5406 Å | scan rate: 0.5°/min | step size: 0.02°(2θ), 2θ range: 10–80° | optics: Monochromator |
| Instrument for BET Surface Area Analysis | Anton Paar QuantaChrome NOVA |
| Adsorption Gas for BET Surface Area Analysis | N₂, Bath temperature: 77.3 K |
| Instrument for Particle Size Distribution (Laser Diffraction) | Beckman Coulter LS 13 320 |
| Medium/Fluid for Particle Size Distribution | 18 Megaohm DI-Water |
| Particle Size at D10 | ~18.31 µm (measured with laser diffraction method) |
| Particle Size at D25 | ~25.43 µm (measured with laser diffraction method) |
| Particle Size at D50 | ~34.53 µm (measured with laser diffraction method) |
| Particle Size at D75 | ~45.39 µm (measured with laser diffraction method) |
| Particle Size at D90 | ~56.02 µm (measured with laser diffraction method) |
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