The XT 40% Silver on Vulcan XC-72R Grade R catalyst manufactured by Fuel Cells ETC is a fine powder that can be used as an electrocatalyst in electrochemical devices and as a heterogeneous catalyst for the synthesis of various organics, such as:
- Alkaline fuel cell cathode catalyst (ORR)
- Metal-air battery air electrodes (Zn-air, Al-air)
- CO₂ electrolysis to CO
- Chlor-alkali oxygen depolarized cathodes
- Electrochemical sensors
- Conductive inks / printed electronics
- Antimicrobial coatings & filters
- Hydrogen peroxide electrogeneration
- Wastewater catalytic treatment
- EMI shielding / conductive polymer additives
- Selective oxidation of alcohols to aldehydes
- Alcohol to ketone oxidation
- Benzyl alcohol oxidation
- Oxidative coupling of amines
- Nitroaromatic reduction to amines
- Transfer hydrogenation reactions
- Oxidation of VOC organics
- Epoxidation support catalyst systems
- Selective alkyne to alkene reduction
- Hydrogen activation in tandem systems
- Cyclization reactions
- Click-type azide/alkyne variants
- A³ coupling (aldehyde + alkyne + amine)
- C–H functionalization (specialty cases)
- Click-type azide/alkyne variants
- Alkyne activation chemistry
- Dehalogenation reactions
- Halide abstraction catalysis
- Isomerization reactions
- Photocatalytic organic transformations
- Radical-mediated oxidations
- and many other electrochemical and non-electrochemical end use cases
This product has a BET surface area of ~94-124 m²/gram. The average crystallite size for Ag nanoparticles is calculated as ~36.61 nm for this product. The average particle size for this supported catalyst material is ~32.6 microns.
40% Silver on Vulcan XC-72R Grade R Technical Specification Sheet
| FCE Catalyst Properties | |
| Appearance | Fine, porous black powder |
| Molecular Formula | ~40 wt % Ag, ~60 wt % Vulcan carbon (XC72R) |
| Molecular Weight | Not applicable (heterogeneous composite) |
| Purity | > 99.9% (3N) |
| Particle Morphology | Aggregated clusters of primary Ag nanoparticles supported on high surface area carbon black |
| Average Particle Size | ~32.6 µm (D₅₀, Laser Diffraction) |
| Particle Size Range | 0 - 100 microns (measured with laser diffraction method) |
| BET Surface Area | ~94 - 124 m2/gram |
| Bulk Density | ~0.2 – 0.32 g cm⁻³ |
| Color | Black |
| Structure | Face‑centered cubic (fcc) Silver (0) |
| Database Reference | COD Card No. (9011607); JCPDS No. (04‑0783) |
| Space Group | Fm-3m |
| Secondary Phases | None detected (only amorphous carbon support) (via PXRD) |
| Instrument for Powder XRD | Instrument: Rigaku MiniFlex 300/600 Cu-Kα radiation (λ = 1.5406 Å | scan rate: 0.5°/min | step size: 0.02°(2θ), 2θ range: 10–80° | optics: Monochromator |
| Instrument for BET Surface Area Analysis | Anton Paar QuantaChrome NOVA |
| Adsorption Gas for BET Surface Area Analysis | N₂, Bath temperature: 77.3 K |
| Instrument for Particle Size Distribution (Laser Diffraction) | Beckman Coulter LS 13 320 |
| Medium/Fluid for Particle Size Distribution | 18 Megaohm DI-Water |
| Particle Size at D10 | ~15.77 µm (measured with laser diffraction method) |
| Particle Size at D25 | ~23.58 µm (measured with laser diffraction method) |
| Particle Size at D50 | ~32.63 µm (measured with laser diffraction method) |
| Particle Size at D75 | ~42.31 µm (measured with laser diffraction method) |
| Particle Size at D90 | ~50.78 µm (measured with laser diffraction method) |
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